The Uses of The Al-Faidiyah Formation Oligocene-Miocene in The Drilling Mud Fluids (Bentonite) at Umm Ar Razam, North-East Libya

Authors

  • Saad K. El Ebaidi Earth Sciences Department, University of Benghazi, P.O.B. 9480, Benghazi, Libya

DOI:

https://doi.org/10.59743/jmset.v1i2.125

Keywords:

Umm Ar Razam, Al Faidiyah Formation, Faidia Clay Member, Fatayah, Hematite, Libya

Abstract

The lower member (Faidia Clay) of the Oligocene-Miocene Al Faidiyah Formation at Umm Ar Razam Quarry, northeast Libya has been investigated for its potential as a chemical additive (bentonite) in drilling oil wells. The thickness in outcrop of the examined clay unit is variable but information from the subsurface indicates a maximum thickness of about 25 m. Normally, these clay deposits have a dark green color that becomes brown when weathered. When wet, the clay forms a very plastic sticky mass with soap-like textures. A number of mineralogical, chemical, and physicochemical laboratory analyses using X-ray diffraction (XRD), scanning electron microscopy (SEM-SE & SEM-BSE), X-ray fluorescence (XRF), ion exchange capacity (CEC) and surface area have been made in order to characterize the grade and quality of the examined clays. The overall results show that montmorillonite represents the highest percentage (46 %), minor kaolinite (36 %), and trace chlorite (4 %). Other minerals of heterogeneous mixtures of non-clay minerals such as fine quartz grains, calcite, dolomite, gypsum, K-feldspar, ilmenite, anatase, and hematite are also recognized. The presence of a heterogeneous mixture of non-clay minerals reduces the rheological and physical properties as well as detracts from the commercial performance of the Faidia clay. The unprocessed clay and clay after treatment with the addition of up to 6 % of Na2CO3, did not achieve a swelling volume comparable with standard bentonite. The Faidia Limestone Member (the upper part of the Al Faidiyah Formation) is characterized by very high purity in Al Fatayah Quarry. It is extensively used for concrete aggregates, road tiles, blocks, paints, carpets, the cement industry, papers, pharmaceuticals, water treatment, agriculture, and plastics. The equivalent member in Umm Ar Razam Quarry has a lower grade due to the presence of other carbonates (dolomite) and non-carbonates such as quartz, clay, and glauconite minerals. Fossil contents and lithological nature indicate that this is a typical shelf environment.

References

Alami, M.R., and Salem G. (1981). Bentonite clay of Al Jabal Al Akhdar. Petrol. Res. Cent. (PRC), 33PP.

Anand R.R., and Gilkes R.J. (1984). Weathering of ilmenite in lateritic Pallid. Clays and Clay Minerals, 32: 363-374.

Babu D.S.S., Thomas K.A., Mohan P.N, and Damodaran A.D. (1994). Alteration of ilmenite in the Manavalakurichi deposit, India. Clays and Clay Minerals, 42: 567-571.

Khameiss B., Hoyt W., El Ebaidi S. K., Muftah A. M., Klaus J., and Budd A. (2016). A Preliminary Documentation of the Coral Reefs from Libya. Open Journal of Geology, 6(4): 260.

Berner R.A. (1971). Principles of chemical sedimentology. New York, 159-191.

Carrol D. (1970). Clay Mineral: A guide to their X-ray identification. USA, 80PP.

Carter D.L., Heilman M.D., and Gonzalez C.L. (1965). Ethylene glycol monoethyl ether for determining surface area of silicate minerals. Soil Science, 100(5): 356-360.

Christidis G., and Scott P.W. (1993). Laboratory evaluation of bentonites. Ind. Minerals, 311: 51-57.

Deer W.A., Howie R.A., and Zussman J. (1992). An Introduction to the rock forming minerals. 2nd edition, Longman, 696PP.

El Ebaidi S.K. (1999). Evaluation of limestone and associated clays as industrial raw materials in NE Libya. PhD thesis, University of Manchester, UK 386PP.

El Ebaidi S.K., and Bakar A.M. (1991). Bentonite Mining Project. Clays of Umm Ar Razam Area: Results of Analyses and Tests. Technical Report, National Oil Corporation, Tripoli, 173PP.

Flinter B.H. (1959). The alteration of Malayan ilmenite grains and the question of "arizonite" Econ. Geol., 54: 720-729.

Gale S.J., and Hoare, P.G. (1991). Quaternary sediments. Petrographic methods for the study of unlithified rocks. Belhaven Press, New York, USA, 323PP.

Grey I.E., and Reid A.F. (1975). The of pseudorutile and its role in the alteration of ilmenite, Amer. Mineral., 60: 898-906.

Grim R.E. (1968). Clay mineralogy. 2nd edition, McGraw Hill, New York, USA, 596PP.

Harries P.M. (1979). Limestone and dolomite. Mineral Resources Consultative Committee. Minerals Strategy and Economics Research Unit. Institute of Geological Sciences. Mineral Dossier no. 23, 111PP.

Inglethorpe S.D.J., Morgan D.J., Highley D.E., and Bloodworth A.J. (1993). Bentonite. Technical report WG/93/20. Mineralogy and Petrology Series. Industrial mineral laboratory manual, British Geological Survey, 115PP.

Lat J., and Zamarsky V. (1992). The report on classification, evaluation and possible mining and processing methods of the potential bentonite deposit in Umm Ar Razam area in Libya. PRC, National Oil Corporation, 200PP.

Moore D.M., and Renolds R.C. (1997). X-ray diffraction and the identification and analysis of clay minerals. 2nd Ed., Oxford, 378PP.

Moorlock B.S.P., and Highly D.E. (1991). An appraisal of fuller's earth resources in England and Wales. British Geological Survey. Technical report WA/91/75.

Morgan D.J. (1994). Minerals for development. Mineralogy and Petrology Group, British Geological Survey, Technical report WA/94/13, 19PP.

Odom I.E. (1984). Smectite clay minerals: properties and uses. Phil. Trans. R. Soc. Lond., A331: 391-409.

PRC (Petroleum Research Centre) (1987). Evaluation of bentonite clay from Umm Ar Razam area. National Oil Corporation, prepared by bentonite project group.

Pietersz C.R. (1968). Proposed nomenclature of rock units in northern Cyrenaica. In: Geology and archaeology of northern Cyrenaica, Libya (Editor Barr F.T.). Petrol. Explor. Soc. Libya, 10th Annual Field Conf., 125-148.

Sassi S. (1991). Bentonite mining project, Libya. Results of analyses and tests. University of Tunis II. Tunisia, 174PP.

Temple A.K. (1966). Alteration of ilmenite. Econ. Geol., 61: 695-714.

Tucker M. (1988). Techniques in Sedimentology. Blackwell Science, 394PP.

Tucker M. (1991). Sedimentary petrology, an introduction to the origin of sedimentary rocks. 2nd edition, Blackwell Science, 260PP.

Velde B. (1992). Introduction to clay minerals, chemistry, origins, uses and environmental significance. Chapman and Hall, London, 198PP.

Waston D.M., and Arhuma, (1992). Evaluation of bentonitic clays of Umm Ar Razam area, Libya as potential drilling muds. PRJ, 4: 46-51.

Downloads

Published

2015-12-31

How to Cite

El Ebaidi , S. K. (2015). The Uses of The Al-Faidiyah Formation Oligocene-Miocene in The Drilling Mud Fluids (Bentonite) at Umm Ar Razam, North-East Libya. Journal of Marine Sciences and Environmental Technologies, 1(2), E 51–67. https://doi.org/10.59743/jmset.v1i2.125

Issue

Section

المقالات