Removal of Arsenic, Fluoride, and Lead from Wastewater Using Novel Polyinorganic Coagulants

Authors

  • Fathy M. M. Ahmed Faculty of Marine Resources, Alasmarya Islamic University, Libya.
  • Khaled A. Falous Faculty of Science, Alasmarya Islamic University, Libya.
  • Moktar M. Aburzeza Faculty of Science, Alasmarya Islamic University, Libya.

DOI:

https://doi.org/10.59743/jmset.v1i1.135

Keywords:

Rice husk ash, Active silica, Sodium silicate, Polyinorganic coagulants, Pollutants removal

Abstract

The present study highlights to the removal of some dangerous pollutants such as lead, arsenic, and fluoride from wastewater. Treatment using a novel polyinorganic coagulants, the eight novel polyinorganic coagulants were prepared, and characterized namely, poly aluminum chloride (PACl) polyaluminum chloride silicate (PAClSi), polyaluminum hydroxy sulphate (PAHS), polyaluminum hydroxy sulphate silicate (PAHSSi), polyferric chloride (PFeCl), polyferric chloridesilicate (PFeClSi), polyaluminum ferric chloride (PAlFeCl), and polyaluminum ferric chloride silicate (PAlFeClSi). The application was carried out for the removal of pollutants from wastewater using these novel polyinorganic coagulants. It was found that the maximum percentages of removal of Pb2+, AS3+, and F- ions from wastewater reached 99.98, 97, and 99%, using novel polyinorganic coagulants PAHSSi, PAlFeClSi, and PAlFeClSi respectively. Therefore, polyinorganic coagulant impregnated with silica was considered as a good coagulant for wastewater treatment due to its low cost and good efficiency in this application, as well as it will solve the problem of water shortage and to sustains a non-conventional water resource.

References

Aboabboud M., Ibrahim H.G., Okasha A., and Elatrash M. S. (2013). Investigation of Chromium Removal by Adsorption/Precipitation Techniques using Solid Waste Material. In: Digital Proceeding of the (ICOEST’2013), 18-21 June, Cappadocia, Nevsehir, Turkey. Journal of Selcuk University Natural and Applied Science, Special Issue: 538-545.

Abo-El-Enein S.A., Eissa M.A., Diafullah A.A., Rizk M.A., & Mohamed F.M. (2009). Removal of some heavy metals ions from wastewater by copolymer of iron and aluminum impregnated with active silica derived from rice husk ash. Journal of Hazardous Materials, 172(2): 574-579.‏

Abo-El-Enein S.A., Eissa M.A., Diafullah A.A., Rizk M.A., & Mohamed F.M. (2011). Utilization of a low cost agro-residue for production of coagulant aids and their applications. Journal of Hazardous Materials, 186(2): 1200-1205.

Ahmed F.M.M. (2009). Treatment of some water pollutants using novel sorbent materials. PhD Thesis, Ain Shams University, Egypt.

Al-Meshragi M.A., Ibrahim H.G, and Okasha A.Y. (2009). Removal of trivalent chromium from aquatic environment by cement kiln dust: Batch studies. In: IAENG Transactions engineering Technologies Vol. (2), 1127(1):74-85. American Institute of Physics, Conference Proceedings.

Bellack E. (1971). Arsenic removal from potable water. Journal of the American Water Works Association, 63(7): 454-458.

Bin Jusoh A., Cheng W.H., Low W.M., Nora’aini A., & Noor M.M.M. (2005). Study on the removal of iron and manganese in groundwater by granular activated carbon. Desalination,

(1): 347-353.‏

Della V.P., Kühn I., & Hotza D. (2002). Rice husk ash as an alternate source for active silica production. Materials Letters, 57(4): 818-821.

DeMarco M.J., SenGupta A.K., & Greenleaf J.E. (2003). Arsenic removal using a polymeric/inorganic hybrid sorbent. Water Research, 37(1): 164-176.

Federation W.E. (FEW), & American Public Health Association (APHA) (2005). Standard methods for the examination of water and wastewater. 19th ed., American Public Health Association (APHA): Washington DC.

Foletto E.L., Gratieri E., Oliveira L.H.D., & Jahn, S.L. (2006). Conversion of rice hull ash into soluble sodium silicate. Materials Research, 9(3): 335-338.

Gupta A.S. (2002). Environmental separation of heavy metals.‏ Lewis Publishers, New York.

‏Jekel M.R. (1994). Removal of arsenic in drinking water treatment. John Wiley and Sons LTD, New York, 6: 119–130.

Kalapathy U., Proctor A., & Shultz J. (2000). A simple method for production of pure silica from rice hull ash. Bioresource Technology, 73(3): 257-262.

Kartinen E.O. & Martin C.J. (1995). An overview of arsenic removal processes. Desalination, 103(1): 79-88.‏

Kaur S., Walia T.P.S., & Mahajan R.K. (2008). Comparative studies of zinc, cadmium, lead and copper on economically viable adsorbents. Journal of Environmental Engineering and Science, 7(1): 83-90.‏

Kim M.J. & Nriagu J. (2000). Oxidation of arsenite in groundwater using ozone and oxygen. Science of the Total Environment, 247(1): 71-79.‏

Krishnarao R.V., Mahajan Y.R., & Kumar T.J. (1998). Conversion of raw rice husks to SiC by pyrolysis in nitrogen atmosphere. Journal of the European Ceramic Society, 18(2): 147-152.‏

Krishnarao R.V., Subrahmanyam J., & Kumar T.J. (2001). Studies on the formation of black particles in rice husk silica ash. Journal of the European Ceramic Society, 21(1): 99-104.‏

Molnár L.U., Virčíkova E., & Lech P. (1994). Experimental study of As(III) oxidation by hydrogen peroxide. Hydrometallurgy, 35(1): 1-9.‏

Munter R., Ojaste H., & Sutt J. (2005). Complexed iron removal from groundwater. Journal of Environmental Engineering, 131(7): 1014-1020.

Namasivayam C., & Ranganathan K. (1995). Removal of Cd(II) from wastewater by adsorption on “waste” Fe(III) Cr (III) hydroxide. Water Research, 29(7): 1737-1744.‏

Okasha A.Y. & Ibrahim H.G. (2010). Removal of Cu2+ Ions from Aqueous Solutions by Adsorption on a Libyan Soil. J. of Environmental Science and Engineering, 4(10):9-15.

Okasha A.Y., Ibrahim H.G., Elatrash M.S., and Marie A.A. (2012). Removal of Cadmium from Aqueous Solutions Using Adsorption Technique: Kinetics and Equilibrium. International Journal of Environment and Bioenergy, 1(2): 105-118.

Patterson J.W. (1985). Industrial wastewater treatment technology.‏ Science Publishers, New York.

Reddad Z., Gerente C., Andres Y., & Le Cloirec P. (2002). Adsorption of several metal ions onto a low-cost biosorbent: kinetic and equilibrium studies. Environmental science & technology, 36(9): 2067-2073.‏

Riveros H., & Garza C. (1986). Rice husks as a source of high purity silica. Journal of Crystal Growth, 75(1): 126-131.‏

Viraraghavan T., Subramanian K.S., & Aruldoss J.A. (1999). Arsenic in drinking water—problems and solutions. Water Science and Technology, 40(2): 69-76.‏

Wasay S.A., Tokunaga S., & Park S.W. (1996). Removal of Hazardous Anions from Aqueous Solutions by La (III)-and Y (III)-lmpregnated Alumina. Separation science and technology, 31(10): 1501-1514.‏

Yalcin N. & Sevinc V. (2001). Studies on silica obtained from rice husk. Ceramics International, 27(2): 219-224.‏

Yuan Y.L., Wen Y.Z., Li X.Y., & Luo S.Z. (2006). Treatment of wastewater from dye manufacturing industry by coagulation. Journal of Zhejiang University Science A, 7(2): 340-344.‏

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Published

2015-06-30

How to Cite

Ahmed, F. M. M., Falous, K. A., & Aburzeza, M. M. (2015). Removal of Arsenic, Fluoride, and Lead from Wastewater Using Novel Polyinorganic Coagulants. Journal of Marine Sciences and Environmental Technologies, 1(1), E 1–10. https://doi.org/10.59743/jmset.v1i1.135

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